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Get Free AccessElite cliques: Palladium clusters with three and four atoms were found to be the catalytically active species for ligand-free palladium-catalyzed CC bond-forming reactions. These palladium cluster species could be stabilized in water and stored for long periods of time for use on demand with no loss of activity. High yields of products and turnover frequencies (TOFs) of up to 10(5) h(-1) were observed.
Antonio Leyva‐Pérez, Judit Oliver‐Meseguer, Paula Rubio‐Marqués, Avelino Avelino (2013). Water‐Stabilized Three‐ and Four‐Atom Palladium Clusters as Highly Active Catalytic Species in Ligand‐Free CC Cross‐Coupling Reactions. Angewandte Chemie International Edition, 52(44), pp. 11554-11559, DOI: 10.1002/anie.201303188.
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Type
Article
Year
2013
Authors
4
Datasets
0
Total Files
0
Language
English
Journal
Angewandte Chemie International Edition
DOI
10.1002/anie.201303188
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