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Get Free AccessUsing models derived from the X-ray structure of photosystem II, it is shown that the oxygen evolving complex in the S(2) state exists in two energetically similar and interconvertible forms. A longstanding question regarding the spectroscopy of the catalyst is thus answered: one form corresponds to the multiline g=2.0 EPR signal (see picture, right; O red, Mn purple, Ca yellow), and the other to the g≥4.1 signals (left).
Dimitrios A. Pantazis, William Ames, Nicholas J. Cox, Wolfgang Lubitz, Frank Neese (2012). Two Interconvertible Structures that Explain the Spectroscopic Properties of the Oxygen‐Evolving Complex of Photosystem II in the S<sub>2</sub> State. Angewandte Chemie International Edition, 51(39), pp. 9935-9940, DOI: 10.1002/anie.201204705.
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Type
Article
Year
2012
Authors
5
Datasets
0
Total Files
0
Language
English
Journal
Angewandte Chemie International Edition
DOI
10.1002/anie.201204705
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