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Get Free Access(Attention for corrosion science, the abstract must not exceed more than 100 words) In this research, first a multi-analytical approach was carried out to propose a mechanistic model for the formation of the thermal oxide film on low Cr stainless steel. It describes the effects of kinetically and thermodynamically driven phenomena on the growth of a Fe-Cr complex oxide film at 950℃. Second, the behavior of the thermal oxide film in the presence of fluoride ions, as a relevant pickling agent in conversion treatment, was investigated. It was shown that fluoride ions enter the oxide film and form a complex with Fe and preferentially dissolve hematite islands through a complexation mechanism.
Mohaddese Nabizadeh, Clément Boissy, Kitty Baert, Steven Goderis, Heidi Ottevaere, Herman Terryn, Tom Hauffman (2020). The mechanism of thermal oxide film formation on low Cr martensitic stainless steel and its behavior in fluoride-based pickling solution in conversion treatment. Corrosion Science, 181, pp. 109206-109206, DOI: 10.1016/j.corsci.2020.109206.
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Type
Article
Year
2020
Authors
7
Datasets
0
Total Files
0
Language
English
Journal
Corrosion Science
DOI
10.1016/j.corsci.2020.109206
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