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Get Free AccessWe report electron paramagnetic resonance measurements on single crystalline and powder samples of ${\mathrm{Nd}}_{0.5}{\mathrm{Ca}}_{0.5}{\mathrm{MnO}}_{3}$ across the charge-ordering transition at ${T}_{\mathrm{co}}=240\mathrm{K}$ down to the antiferromagnetic ordering transition at ${T}_{N}=140\mathrm{K}.$ The changes in the linewidth, g-factor and intensity as functions of temperature are studied to understand the nature of spin-dynamics in the system. We explain the observed large decrease in the linewidth from ${T}_{N}$ to ${T}_{\mathrm{co}}$ in terms of motional narrowing caused by the hopping of the Jahn--Teller polarons yielding an activation energy of ${E}_{a}=0.1\mathrm{}\mathrm{eV}.$ Similar analysis of data on ${\mathrm{Pr}}_{0.6}{\mathrm{Ca}}_{0.4}{\mathrm{MnO}}_{3}$ published earlier gives ${E}_{a}=0.2\mathrm{eV}.$ Below ${T}_{\mathrm{co}},$ the g-value increases continuously suggesting a gradual strengthening of the orbital ordering. We give a qualitative explanation of the maximum in the asymmetry ratio A/B observed at ${T}_{\mathrm{co}}$ and its temperature dependence in single crystal spectra which also supports the model of motional narrowing.
Janhavi P. Joshi, Rajeev Gupta, A. K. Sood, S. V. Bhat, A. R. Raju, Cnr Rao (2001). Temperature-dependent electron paramagnetic resonance studies of charge-ordered<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Nd</mml:mi></mml:mrow><mml:mrow><mml:mn>0.5</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow><mml:mrow><mml:mn>0.5</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal…. Physical review. B, Condensed matter, 65(2), DOI: 10.1103/physrevb.65.024410.
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Type
Article
Year
2001
Authors
6
Datasets
0
Total Files
0
Language
English
Journal
Physical review. B, Condensed matter
DOI
10.1103/physrevb.65.024410
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