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Get Free AccessA chiral vanadyl salen complex having two peripheral trimethoxysilyl groups has been used to obtain a chiral periodic mesoporous organosilica having MCM-41 periodicity and the two Si-CH2 groups anchored on the framework; this solid induces 30% enantioselectivity in the cyanosilylation of benzaldehyde.
Carlos Baleizão, Bárbara Gigante, Debasish Das, Mercedes Ãlvaro, Hermenegildo Garcı́a, Avelino Avelino (2003). Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO). Chemical Communications, pp. 1860-1861, DOI: 10.1039/b304814d.
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Type
Article
Year
2003
Authors
6
Datasets
0
Total Files
0
Language
English
Journal
Chemical Communications
DOI
10.1039/b304814d
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