Symmetry‐Mismatch‐Induced Ferromagnetism in the Interfacial Layers of CaRuO₃/SrTiO₃ Superlattices

Abstract By modifying the entangled multi‐degrees of freedom of transition‐metal oxides, interlayer coupling usually produces interfacial phases with unusual functionalities. Herein, a symmetry‐mismatch‐driven interfacial phase transition from paramagnetic to ferromagnetic state is reported. By constructing superlattices using CaRuO 3 and SrTiO 3 , two oxides with different oxygen octahedron networks, the tilting/rotation of oxygen octahedra near interface is tuned dramatically, causing an angle increase from ≈150° to ≈165° for the RuORu bond. This in turn drives the interfacial layer of CaRuO 3 , ≈3 unit cells in thickness, from paramagnetic into ferromagnetic state. The ferromagnetic order is robust, showing the highest Curie temperature of ≈120 K and the largest saturation magnetization of ≈0.7 µ B per formula unit. Density functional theory calculations show that the reduced tilting/rotation of RuO 6 octahedra favors an itinerant ferromagnetic ground state. This work demonstrates an effective phase tuning by coupled octahedral rotations, offering a new approach to explore emergent materials with desired functionalities.