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  5. Structure stability, fracture, and tuning mechanism of CdSe nanobelts

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Article
en
2007

Structure stability, fracture, and tuning mechanism of CdSe nanobelts

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en
2007
Vol 90 (11)
Vol. 90
DOI: 10.1063/1.2713172

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Zhong Lin Wang
Zhong Lin Wang

Beijing Institute of Technology

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Zhongwu Wang
Ken Finkelstein
Chris Ma
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Abstract

High pressure synchrotron x-ray diffraction studies have been conducted to explore the structural stability, phase transformation, and resulting mechanisms of CdSe nanobelts. 25-nm-thick wurtzite CdSe nanobelts transform to a rocksalt structure with in situ fracture at 4.0GPa; this is greater than the transition pressure of 2.5GPa in bulk and 25nm nanoparticle. Decompression results in the formation of wurtzite and sphalerite at 1.2GPa. Total Gibbs free energy calculations demonstrate that the low surface energy ±{21¯0} facets are fully responsible for the enhancement of structure stability. A strongest particle size for the rocksalt phase was determined ∼12nm, providing a significant constraint for the fracture of nanobelts and size-tuned enhancement of mechanical properties.

How to cite this publication

Zhongwu Wang, Ken Finkelstein, Chris Ma, Zhong Lin Wang (2007). Structure stability, fracture, and tuning mechanism of CdSe nanobelts. , 90(11), DOI: https://doi.org/10.1063/1.2713172.

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Publication Details

Type

Article

Year

2007

Authors

4

Datasets

0

Total Files

0

Language

en

DOI

https://doi.org/10.1063/1.2713172

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