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Get Free AccessHigh pressure synchrotron x-ray diffraction studies have been conducted to explore the structural stability, phase transformation, and resulting mechanisms of CdSe nanobelts. 25-nm-thick wurtzite CdSe nanobelts transform to a rocksalt structure with in situ fracture at 4.0GPa; this is greater than the transition pressure of 2.5GPa in bulk and 25nm nanoparticle. Decompression results in the formation of wurtzite and sphalerite at 1.2GPa. Total Gibbs free energy calculations demonstrate that the low surface energy ±{21¯0} facets are fully responsible for the enhancement of structure stability. A strongest particle size for the rocksalt phase was determined ∼12nm, providing a significant constraint for the fracture of nanobelts and size-tuned enhancement of mechanical properties.
Zhongwu Wang, Ken Finkelstein, Chris Ma, Zhong Lin Wang (2007). Structure stability, fracture, and tuning mechanism of CdSe nanobelts. , 90(11), DOI: https://doi.org/10.1063/1.2713172.
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Type
Article
Year
2007
Authors
4
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.1063/1.2713172
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