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Get Free AccessSilver micro- and nanocrystals with sizes of ∼2−3.5 μm and ∼50−100 nm were uniaxially compressed under nonhydrostatic pressures (strong deviatoric stress) up to ∼30 GPa at room temperature in a symmetric diamond-anvil cell and studied in situ using angle-dispersive synchrotron X-ray diffraction. A cubic to trigonal structural distortion along a 3-fold rotational axis was discovered by careful and comprehensive analysis of the apparent lattice parameter and full width at half-maximum, which are strongly dependent upon the Miller index and crystal size.
Qixun Guo, Yusheng Zhao, Zhongwu Wang, Sara E. Skrabalak, Zhijun Lin, Younan Xia (2008). Size Dependence of Cubic to Trigonal Structural Distortion in Silver Micro- and Nanocrystals under High Pressure. , 112(51), DOI: https://doi.org/10.1021/jp809177n.
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Type
Article
Year
2008
Authors
6
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.1021/jp809177n
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