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Get Free AccessITQ-2 is the first member of the class of delaminated zeolite precursors. Here we present data to corroborate its proposed structure. Sorption measurements show that ITQ-2 no longer contains large 12-membered-ring (12MR) cavities typical for the non-delaminated MWW-type zeolite, and only retained the 10-membered-ring (10MR) system inside the layer. Adsorption and high resolution transmission electron microscopy (HR-TEM) experiments confirm that delamination allows the ITQ-2 layer to retain most of its structural integrity. The catalytic properties of ITQ-2 are in agreement with those expected from an aluminosilicate that combines a large, catalytically active external surface with the 10MR channel system.
Avelino Avelino, V. Fornés, J.M. Guil, Sibele B. C. Pergher, Th. L. M. Maesen, J. G. Buglass (2000). Preparation, characterisation and catalytic activity of ITQ-2, a delaminated zeolite. Microporous and Mesoporous Materials, 38(2-3), pp. 301-309, DOI: 10.1016/s1387-1811(00)00149-9.
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Type
Article
Year
2000
Authors
6
Datasets
0
Total Files
0
Language
English
Journal
Microporous and Mesoporous Materials
DOI
10.1016/s1387-1811(00)00149-9
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