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Get Free AccessBioinspired dual activation: Dual activation within the bimetallic pocket of a bioinspired dicopper(II) complex suitably places two phenolato substrates for preferred ortho-ortho coupling. Spectroscopic data and the molecular structure of a unique Cu(6) complex isolated from the reaction mixture reveal a novel terphenolato ligand and provide a clue about the activation mechanism (see picture).
A. Prokofieva, Sebastian Dechert, Christian U. Große, In Memory: G.M. Sheldrick (1942–2025), Franc Meyer (2009). Oxidative <i>ortho</i> CC Coupling of 4‐Ethylphenol by Dual Substrate Activation at a Bioinspired Dicopper Complex—Trapping of an Unusual Oligophenolic Cu<sub>6</sub> Species. Chemistry - A European Journal, 15(20), pp. 4994-4997, DOI: 10.1002/chem.200900424.
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Type
Article
Year
2009
Authors
5
Datasets
0
Total Files
0
Language
English
Journal
Chemistry - A European Journal
DOI
10.1002/chem.200900424
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