0 Datasets
0 Files
Get instant academic access to this publication’s datasets.
Join our academic network to download verified datasets and collaborate with researchers worldwide.
Get Free AccessThe kinetics for the hydrodechlorination reaction of 2-chloro-1,1,1,2-tetrafluoroethane (CF3-CFClH), 1,1-dichlorotetrafluoroethane (CF3-CFCl2), and 1,1,1-trichloro-2,2,2-trifluoroethane (CF3-CCl3) are reported on three model catalysts: a palladium foil and two Pd single crystals of (111) and (100) orientation. The turnover rates for the hydrodechlorination of 1,1-dichlorotetrafluoroethane were similar for the three model catalysts tested, suggesting that the reaction is not sensitive to the structure of the catalyst. However, the turnover rates for hydrodechlorination of the three compounds tested are very dependent on the structure of the reactant, spanning a range of seven orders of magnitude. The experimentally determined reaction orders for the main products are about 1 in the reactant, 0.5 in H2 and -1 in HCl. The derived reaction steps based on these orders consist of the adsorption of the chlorofluorocarbon (rate determining step) and equilibrated steps between gas phase H2, gas phase HCl and adsorbed hydrogen and chlorine atoms. This chemistry is important in the manufacture of many new compounds that use hydrodechlorination as an intermediate step.
Fabio H. Ribeiro, Gabor Somorjai (2000). Kinetics for the Hydrodechlorination of Chlorofluorocarbons over Model Palladium CatalystsDOI: https://doi.org/10.1021/bk-2001-0766.ch015,
Datasets shared by verified academics with rich metadata and previews.
Authors choose access levels; downloads are logged for transparency.
Students and faculty get instant access after verification.
Type
Chapter in a book
Year
2000
Authors
2
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.1021/bk-2001-0766.ch015
Access datasets from 50,000+ researchers worldwide with institutional verification.
Get Free AccessYes. After verification, you can browse and download datasets at no cost. Some premium assets may require author approval.
Files are stored on encrypted storage. Access is restricted to verified users and all downloads are logged.
Yes, message the author after sign-up to request supplementary files or replication code.
Join 50,000+ researchers worldwide. Get instant access to peer-reviewed datasets, advanced analytics, and global collaboration tools.
✓ Immediate verification • ✓ Free institutional access • ✓ Global collaboration