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  5. Influence of radical initiators in gold catalysis: Evidence supporting trapping of radicals derived from azobis(isobutyronitrile) by gold halides

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Article
English
2006

Influence of radical initiators in gold catalysis: Evidence supporting trapping of radicals derived from azobis(isobutyronitrile) by gold halides

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English
2006
Journal of Catalysis
Vol 245 (1)
DOI: 10.1016/j.jcat.2006.10.003

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Avelino Avelino
Avelino Avelino

Instituto de Tecnología Química

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Mercedes Álvaro
Carmela Aprile
Avelino Avelino
+2 more

Abstract

Gold halides (AuCl3, HAuCl4, and AuCl) efficiently trap the radicals generated in the room-temperature photolysis of azobis(isobutyronitrile) (AIBN) to give an organogold H[(CH3)2CCN]2AuCl2 compound that has been characterized by spectroscopy. The characteristic features of the organogold are a quaternary carbon at 100 ppm on 13C NMR and a HR-MS peak with a molecular formula of C8H13N2AuCl. Catalytic data for cyclohexene aerobic oxidation confirms the beneficial influence of the presence of AIBN on the catalytic activity of Au/CeO2.

How to cite this publication

Mercedes Álvaro, Carmela Aprile, Avelino Avelino, Belén Ferrer, Hermenegildo García (2006). Influence of radical initiators in gold catalysis: Evidence supporting trapping of radicals derived from azobis(isobutyronitrile) by gold halides. Journal of Catalysis, 245(1), pp. 249-252, DOI: 10.1016/j.jcat.2006.10.003.

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Publication Details

Type

Article

Year

2006

Authors

5

Datasets

0

Total Files

0

Language

English

Journal

Journal of Catalysis

DOI

10.1016/j.jcat.2006.10.003

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