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  5. In situ electrochemical surface derivation of cobalt phosphate from a Co(CO<sub>3</sub>)<sub>0.5</sub>(OH)·0.11H<sub>2</sub>O nanoarray for efficient water oxidation in neutral aqueous solution

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Article
en
2017

In situ electrochemical surface derivation of cobalt phosphate from a Co(CO<sub>3</sub>)<sub>0.5</sub>(OH)·0.11H<sub>2</sub>O nanoarray for efficient water oxidation in neutral aqueous solution

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en
2017
Vol 9 (11)
Vol. 9
DOI: 10.1039/c6nr09585b

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Abdullah Mohamed Asiri
Abdullah Mohamed Asiri

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Liang Cui
Danni Liu
Shuai Hao
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Abstract

In this Communication, cobalt phosphate (Co-Pi) has been successfully developed on a Co(CO3)0.5(OH)·0.11H2O nanoarray (CCH NA) on Ti mesh in neutral phosphate-buffered solution (PBS) via in situ electrochemical surface derivation. The resulting core@shell structured CCH@Co-Pi NA/Ti exhibits remarkable activity toward water oxidation with the need of an overpotential of 460 mV to achieve a geometrical catalytic current density of 10 mA cm-2 in 0.1 M PBS, with a high turnover frequency of and long-term electrochemical stability.

How to cite this publication

Liang Cui, Danni Liu, Shuai Hao, Fengli Qu, Gu Du, Jingquan Liu, Abdullah Mohamed Asiri, Xuping Sun (2017). In situ electrochemical surface derivation of cobalt phosphate from a Co(CO<sub>3</sub>)<sub>0.5</sub>(OH)·0.11H<sub>2</sub>O nanoarray for efficient water oxidation in neutral aqueous solution. , 9(11), DOI: https://doi.org/10.1039/c6nr09585b.

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Publication Details

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Article

Year

2017

Authors

8

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0

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0

Language

en

DOI

https://doi.org/10.1039/c6nr09585b

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