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Get Free AccessIn this work, we will report the generation of Au clusters in a purely siliceous MCM-22 zeolite. The catalytic properties of these Au clusters have been tested for the selective oxidation of cyclohexane to cyclohexanol and cyclohexanone (KA-oil). The Au clusters encapsulated in the MCM-22 zeolite are highly active and selective for the oxidation of cyclohexane to KA-oil, which is superior to Au nanoparticles on the same support. These results suggest that Au clusters are highly active for the activation of oxygen to produce radical species.
Lichen Liu, Raúl Arenal, Débora Motta Meira, Avelino Avelino (2019). Generation of gold nanoclusters encapsulated in an MCM-22 zeolite for the aerobic oxidation of cyclohexane. Chemical Communications, 55(11), pp. 1607-1610, DOI: 10.1039/c8cc07185c.
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Type
Article
Year
2019
Authors
4
Datasets
0
Total Files
0
Language
English
Journal
Chemical Communications
DOI
10.1039/c8cc07185c
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