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  5. Differentiating between the diffusion of water and ions from aqueous electrolytes in organic coatings using an integrated spectro-electrochemical technique

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Article
English
2022

Differentiating between the diffusion of water and ions from aqueous electrolytes in organic coatings using an integrated spectro-electrochemical technique

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English
2022
Corrosion Science
Vol 212
DOI: 10.1016/j.corsci.2022.110919

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Herman Terryn
Herman Terryn

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Negin Madelat
Benny Wouters
Ehsan Jalilian
+4 more

Abstract

In this work, the separate diffusion of water and ions through a polyethylene glycol diacrylate (PEGDA) coating was characterized using an integrated spectro-electrochemical technique. The ions ingress front position profile along the thickness of the coating was derived from fitting odd random phase electrochemical impedance spectroscopy (ORP-EIS) data using a physically relevant electrochemical equivalent circuit (EEC). The arrival time of the ions at the coating/metal oxide buried interface obtained from EEC and rapid uptake of water was verified using in situ attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) measurements in Kretschmann geometry integrated in the ORP-EIS set-up.

How to cite this publication

Negin Madelat, Benny Wouters, Ehsan Jalilian, Guy Van Assche, Annick Hubin, Herman Terryn, Tom Hauffman (2022). Differentiating between the diffusion of water and ions from aqueous electrolytes in organic coatings using an integrated spectro-electrochemical technique. Corrosion Science, 212, pp. 110919-110919, DOI: 10.1016/j.corsci.2022.110919.

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Publication Details

Type

Article

Year

2022

Authors

7

Datasets

0

Total Files

0

Language

English

Journal

Corrosion Science

DOI

10.1016/j.corsci.2022.110919

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