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Get Free AccessIn this work, the separate diffusion of water and ions through a polyethylene glycol diacrylate (PEGDA) coating was characterized using an integrated spectro-electrochemical technique. The ions ingress front position profile along the thickness of the coating was derived from fitting odd random phase electrochemical impedance spectroscopy (ORP-EIS) data using a physically relevant electrochemical equivalent circuit (EEC). The arrival time of the ions at the coating/metal oxide buried interface obtained from EEC and rapid uptake of water was verified using in situ attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) measurements in Kretschmann geometry integrated in the ORP-EIS set-up.
Negin Madelat, Benny Wouters, Ehsan Jalilian, Guy Van Assche, Annick Hubin, Herman Terryn, Tom Hauffman (2022). Differentiating between the diffusion of water and ions from aqueous electrolytes in organic coatings using an integrated spectro-electrochemical technique. Corrosion Science, 212, pp. 110919-110919, DOI: 10.1016/j.corsci.2022.110919.
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Type
Article
Year
2022
Authors
7
Datasets
0
Total Files
0
Language
English
Journal
Corrosion Science
DOI
10.1016/j.corsci.2022.110919
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