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Get Free AccessHydrophosphination of styrenes has been accomplished with metal salts for the first time. (CuOTf)2·toluene complex is the catalyst of choice, but CuCl can also be used. “In-situ” EPR and NMR studies suggest Cu(I) as the catalytically active metal species, giving exclusively the anti-Markovnikov product. Phosphine oxides or β-ketophosphine oxides can be prepared in one-pot by oxidation with molecular oxygen.
Antonio Leyva‐Pérez, Alejandro Vidal‐Moya, Jose R. Cabrero‐Antonino, Salem S. Al-Deyab, Saud I. Al–Resayes, Avelino Avelino (2010). Copper(I)-catalyzed hydrophosphination of styrenes. Journal of Organometallic Chemistry, 696(1), pp. 362-367, DOI: 10.1016/j.jorganchem.2010.09.069.
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Type
Article
Year
2010
Authors
6
Datasets
0
Total Files
0
Language
English
Journal
Journal of Organometallic Chemistry
DOI
10.1016/j.jorganchem.2010.09.069
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