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Get Free AccessBlue light-emitting boron 8-hydroxyquinolinate and 8-hydroxyquinaldinate complexes have been formed inside boron zeolites Beta, MCM-22, and ferrierite, and on layered ITQ-2 and ITQ-6 zeolites starting from the corresponding ligands and boron dislodged from framework positions. The luminescence properties, i.e., emission intensity, maximum wavelength, and lifetime of the ship-in-a-bottle quinolinate complexes are strongly modulated by the zeolite host. Besides the species responsible for the photoluminescence, other longer-lived transient species, presumably related to electron transport, are also photochemically generated and have been detected by laser flash photolysis.
Avelino Avelino, Urbano Díaz, Belén Ferrer, Vicente Fornés, María S. Galletero, Hermenegildo Garcı́a (2004). Controlling the Emission of Blue-Emitting Complexes by Encapsulation within Zeolite Cavities. Chemistry of Materials, 16(7), pp. 1170-1176, DOI: 10.1021/cm0347640.
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Type
Article
Year
2004
Authors
6
Datasets
0
Total Files
0
Language
English
Journal
Chemistry of Materials
DOI
10.1021/cm0347640
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