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Get Free AccessZero, one, or three? The role of Au0, AuI, and AuIII cations in the heterogeneous gold catalyst Au/CeO2 was investigated with the copper-free Sonogashira cross-coupling reaction of iodobenzene and phenyl acetylene (see picture). Reactions carried out under both heterogeneous and homogeneous conditions using distinct Au0, AuI, and AuIII species reveal that AuI is the active species for the cross-coupling reaction.
Camino González‐Arellano, Alberto Abad, Avelino Avelino, Hermenegildo Garcı́a, M. Iglesias, Félix Sánchez (2007). Catalysis by Gold(I) and Gold(III): A Parallelism between Homo‐ and Heterogeneous Catalysts for Copper‐Free Sonogashira Cross‐Coupling Reactions. Angewandte Chemie International Edition, 46(9), pp. 1536-1538, DOI: 10.1002/anie.200604746.
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Type
Article
Year
2007
Authors
6
Datasets
0
Total Files
0
Language
English
Journal
Angewandte Chemie International Edition
DOI
10.1002/anie.200604746
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