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Get Free AccessNew high-spin pathways: All four feasible reaction pathways for alkane hydroxylation by nonheme iron(IV)–oxo complexes have been investigated by computational methods. The triplet σ path is too high in energy to be involved in CH bond activation, but the reactivity of the quintet π channel competes with the triplet path and may thus offer a new approach for specific control of CH bond activation by iron(IV)–oxo species (see scheme).
Caiyun Geng, Shengfa Ye, Frank Neese (2010). Analysis of Reaction Channels for Alkane Hydroxylation by Nonheme Iron(IV)–Oxo Complexes. Angewandte Chemie International Edition, 49(33), pp. 5717-5720, DOI: 10.1002/anie.201001850.
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Type
Article
Year
2010
Authors
3
Datasets
0
Total Files
0
Language
English
Journal
Angewandte Chemie International Edition
DOI
10.1002/anie.201001850
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