0 Datasets
0 Files
Get instant academic access to this publication’s datasets.
Yes. After verification, you can browse and download datasets at no cost. Some premium assets may require author approval.
Files are stored on encrypted storage. Access is restricted to verified users and all downloads are logged.
Yes, message the author after sign-up to request supplementary files or replication code.
Join 50,000+ researchers worldwide. Get instant access to peer-reviewed datasets, advanced analytics, and global collaboration tools.
✓ Immediate verification • ✓ Free institutional access • ✓ Global collaborationJoin our academic network to download verified datasets and collaborate with researchers worldwide.
Get Free AccessThe one-pot epoxidation of alkenes with O2 is performed with nano-particulated Au/CeO2 and Ti-MCM-41 silylated materials in the presence of a hydrocarbon and azobis-iso-butyronitrile (AIBN) as a promoter. This initiator is able to form organo-gold species that promote the formation of hydrocarbon (3-methyl-pentane, ethylbenzene, or cumene) hydroperoxides which in the presence of Ti-mesoporous material epoxidize the alkene in good yields. The epoxidation reaction of 1-octene with molecular oxygen ( P O 2 = 12 bars ) at 90°C over AIBN–Au/CeO2 +Ti-MCM-41-silylated catalytic system results in alkene conversions close to 9% (≈40% of the maximum conversion attainable) with epoxide selectivity around 90% when working with cumene as a sacrificial hydrocarbon.
Carmela Aprile, Avelino Avelino, Marcelo E. Domine, Hermenegildo Garcı́a, Chris J. Mitchell (2009). A cascade aerobic epoxidation of alkenes over Au/CeO2 and Ti-mesoporous material by “in situ” formed peroxides. Journal of Catalysis, 264(1), pp. 44-53, DOI: 10.1016/j.jcat.2009.03.010.
Datasets shared by verified academics with rich metadata and previews.
Authors choose access levels; downloads are logged for transparency.
Students and faculty get instant access after verification.
Type
Article
Year
2009
Authors
5
Datasets
0
Total Files
0
Language
English
Journal
Journal of Catalysis
DOI
10.1016/j.jcat.2009.03.010
Access datasets from 50,000+ researchers worldwide with institutional verification.
Get Free Access
