0 Datasets
0 Files
Get instant academic access to this publication’s datasets.
Yes. After verification, you can browse and download datasets at no cost. Some premium assets may require author approval.
Files are stored on encrypted storage. Access is restricted to verified users and all downloads are logged.
Yes, message the author after sign-up to request supplementary files or replication code.
Join 50,000+ researchers worldwide. Get instant access to peer-reviewed datasets, advanced analytics, and global collaboration tools.
✓ Immediate verification • ✓ Free institutional access • ✓ Global collaborationJoin our academic network to download verified datasets and collaborate with researchers worldwide.
Get Free AccessA bisamine aliphatic dithiolate [NiIIN2S2] complex that does yield a metal-based oxidation has been synthesized. A square pyramidal [NiIIIN3S2]+ complex is generated by electrochemical oxidation in the presence of imidazole, mimicking the redox structural changes of NiSOD. In addition, EPR measurements coupled to DFT calculations demonstrate that the metal character in the redox active orbital increases drastically upon imidazole binding, implicating that these geometrical modifications are crucial for the stabilization of the NiIII state.
Marcello Gennari, Maylis Orio, Jacques Pécaut, Frank Neese, Marie‐Noëlle Collomb, Carole Duboc (2010). Reversible Apical Coordination of Imidazole between the Ni(III) and Ni(II) Oxidation States of a Dithiolate Complex: A Process Related to the Ni Superoxide Dismutase. Inorganic Chemistry, 49(14), pp. 6399-6401, DOI: 10.1021/ic100945n.
Datasets shared by verified academics with rich metadata and previews.
Authors choose access levels; downloads are logged for transparency.
Students and faculty get instant access after verification.
Type
Article
Year
2010
Authors
6
Datasets
0
Total Files
0
Language
English
Journal
Inorganic Chemistry
DOI
10.1021/ic100945n
Access datasets from 50,000+ researchers worldwide with institutional verification.
Get Free Access
