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Get Free AccessHCl in solution accepts electron density from Au NPs and partially reduces at room temperature, as occurs with other simple diatomic molecules, such as O2 and H2 . The activation can be run catalytically in the presence of alkynes to give exclusively E-vinyl chlorides, after the regio- and stereoselective transfer of HCl. Based also on this method, vinyl chloride monomer (VCM) can be produced in a milder and greener way than current industrial processes.
Judit Oliver‐Meseguer, Antonio Doménech‐Carbó, Mercedes Boronat, Antonio Leyva‐Pérez, Avelino Avelino (2017). Partial Reduction and Selective Transfer of Hydrogen Chloride on Catalytic Gold Nanoparticles. Angewandte Chemie International Edition, 56(23), pp. 6435-6439, DOI: 10.1002/anie.201700282.
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Type
Article
Year
2017
Authors
5
Datasets
0
Total Files
0
Language
English
Journal
Angewandte Chemie International Edition
DOI
10.1002/anie.201700282
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