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  5. Partial Reduction and Selective Transfer of Hydrogen Chloride on Catalytic Gold Nanoparticles

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Article
English
2017

Partial Reduction and Selective Transfer of Hydrogen Chloride on Catalytic Gold Nanoparticles

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0 Files

English
2017
Angewandte Chemie International Edition
Vol 56 (23)
DOI: 10.1002/anie.201700282

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Avelino Avelino
Avelino Avelino

Instituto de Tecnología Química

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Judit Oliver‐Meseguer
Antonio Doménech‐Carbó
Mercedes Boronat
+2 more

Abstract

HCl in solution accepts electron density from Au NPs and partially reduces at room temperature, as occurs with other simple diatomic molecules, such as O2 and H2 . The activation can be run catalytically in the presence of alkynes to give exclusively E-vinyl chlorides, after the regio- and stereoselective transfer of HCl. Based also on this method, vinyl chloride monomer (VCM) can be produced in a milder and greener way than current industrial processes.

How to cite this publication

Judit Oliver‐Meseguer, Antonio Doménech‐Carbó, Mercedes Boronat, Antonio Leyva‐Pérez, Avelino Avelino (2017). Partial Reduction and Selective Transfer of Hydrogen Chloride on Catalytic Gold Nanoparticles. Angewandte Chemie International Edition, 56(23), pp. 6435-6439, DOI: 10.1002/anie.201700282.

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Publication Details

Type

Article

Year

2017

Authors

5

Datasets

0

Total Files

0

Language

English

Journal

Angewandte Chemie International Edition

DOI

10.1002/anie.201700282

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