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Get Free AccessBiscarbene ligands with two imidazolin-2-ylidene moieties at a chiral dioxolane backbone were used as ligands for gold, rhodium and palladium complexes. All new complexes showed varying degrees of enantioselectivity toward hydrogenation of prochiral alkenes with ees up to 95%.
Avelina Arnanz, Camino González‐Arellano, Alberto Juan, Gonzalo Villaverde, Avelino Avelino, M. Iglesias, Félix Sánchez (2010). New chiral ligands bearing two N-heterocyclic carbene moieties at a dioxolane backbone. Gold, palladium and rhodium complexes as enantioselective catalysts. Chemical Communications, 46(17), pp. 3001-3001, DOI: 10.1039/b922534j.
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Type
Article
Year
2010
Authors
7
Datasets
0
Total Files
0
Language
English
Journal
Chemical Communications
DOI
10.1039/b922534j
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