0 Datasets
0 Files
Get instant academic access to this publication’s datasets.
Yes. After verification, you can browse and download datasets at no cost. Some premium assets may require author approval.
Files are stored on encrypted storage. Access is restricted to verified users and all downloads are logged.
Yes, message the author after sign-up to request supplementary files or replication code.
Join 50,000+ researchers worldwide. Get instant access to peer-reviewed datasets, advanced analytics, and global collaboration tools.
✓ Immediate verification • ✓ Free institutional access • ✓ Global collaborationJoin our academic network to download verified datasets and collaborate with researchers worldwide.
Get Free AccessA heterogeneous ruthenium catalyst consisting of isolated single atoms and disordered clusters stabilized in a N-doped carbon matrix has been synthesized with very good activity and remarkable regioselectivity in the hydroformylation of 1-hexene. The role of the nitrogen heteroatoms has been probed essential to increase the catalyst stability and activity, enabling the stabilization of Ru(II)–N sites according to X-ray photoelectron spectroscopy (XPS) and XANES. Intrinsic size-dependent activity of Ru species of different atomicity has been extracted, correlating the observed reaction rate and the particle size distribution determined by means of aberration-corrected high-angle annular dark-field scanning transmission electron microscopy, permitting the identification of single-atom sites as the most active ones. This catalyst appears as a promising alternative with respect to its heterogeneous counterparts, paving the way for designing improved Ru heterogeneous catalysts.
Francisco Javier Escobar‐Bedia, Miguel López‐Haro, José J. Calvino, Vlad Martin‐Diaconescu, Laura Simonelli, Virginia Pérez‐Dieste, María J. Sabater, Patricia Concepción, Avelino Avelino (2022). Active and Regioselective Ru Single-Site Heterogeneous Catalysts for Alpha-Olefin Hydroformylation. ACS Catalysis, 12(7), pp. 4182-4193, DOI: 10.1021/acscatal.1c05737.
Datasets shared by verified academics with rich metadata and previews.
Authors choose access levels; downloads are logged for transparency.
Students and faculty get instant access after verification.
Type
Article
Year
2022
Authors
9
Datasets
0
Total Files
0
Language
English
Journal
ACS Catalysis
DOI
10.1021/acscatal.1c05737
Access datasets from 50,000+ researchers worldwide with institutional verification.
Get Free Access
