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Dinuclear cadmium(II) complexes with distorted octahedral/monocapped trigonal prism coordination geometries: synthesis, crystal structure, DFT/ TD-DFT calculation and photocatalytic degradation of methylene blue

Abstract

Two Cd(II) complexes [Cd2(L1)2(dca)(NO3)] (1) and [Cd2(L2)2(SCN)(NO3)] (2) (HL1 = 2-methoxy-6-[(2-phenylamino-ethylimino)-methyl]-phenol; and HL2 = 2-[(2-ethylamino-ethylimino)-methyl]-6-methoxy-phenol), have been synthesized and characterized by single crystal structure analysis, IR and mass spectroscopic studies. Both the complexes 1 and 2 possess a triclinic crystal system with space group P 1. In complex 1, geometry around one metal centre is distorted octahedral and other centre is distorted monocapped trigonal prism, whereas in complex 2, both the metal centres possess distorted octahedral geometries. Strong N-H & sdot;& sdot;& sdot;O and weak aromatic C-H & sdot;& sdot;center dot O hydrogen bonding interactions in 1 and strong N-H & sdot;& sdot;& sdot;O and N-H & sdot;& sdot;& sdot;S hydrogen bonding in 2 results 1D and 2D supramolecular structures, respectively. Experimentally determined electronic spectral data have been compared with the calculated data obtained by DFT and TD-DFT calculation. Photocatalytic abilities of 1 and 2 have been examined by using spectroscopic technique and found that in presence of UV light both the complexes catalytically decomposed methylene blue by 54.0 % and 50.3 %, respectively.

article Article

date_range 2024

language English

link Link of the paper

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Saren Dama

Bodensteiner Michael

Manna Subal

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Cd(II) complexes

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Assessment of reinforced concrete building damages following the Kahramanmaraş earthquakes in Malatya, Turkey (February 6, 2023)

Abstract

Earthquakes of magnitude Mw = 7.7 and Mw = 7.6 hit the city of Kahramanmaraş (Turkey) on 6 February 2023. These earthquakes caused serious damage in 11 provinces in Turkey resulting in over 50,000 deaths and huge economic losses with the collapse of thousands of buildings. Two consecutive devastating earthquakes have severely damaged the reinforced concrete building stock located in Malatya. There are many reasons reinforced concrete structures suffer damage under the influence of seismic loads. These reasons can be listed as material and section properties that do not comply with earthquake codes, workmanship defects, ground parameters that are not considered and design errors, as seen in field investigations after earthquakes in Turkey in the past. In this research, a field study was conducted on reinforced concrete buildings damaged after the earthquakes in Malatya province. The causes of structural damages in reinforced concrete buildings between 6–26 years of age were assessed in terms of design and material defects. The structural damages were mainly caused due to insufficient stirrups in structural members, short column, strong beam–weak column, failures of infill walls, soft story type collapse, poor concrete quality, and reinforcement corrosion. In addition to the field investigation, the spectrum relationships created using raw acceleration data obtained from DEMP (Disaster and Emergency Management Presidency) stations in Malatya province were compared with the design response spectra.

article Article

date_range 2024

language English

link Link of the paper

Collapsed buildings

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