H
Halim, Md. Abdul
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Lanthanoid pseudo-Grignard reagents: A review

Abstract

This review covers the progress of the chemistry of divalent lanthanoid pseudo-Grignard, compounds, with E-LnX bonding (E = C, N, O; X = I, Br, Cl, F), especially since the 2002 review of Petrov et al. (2002)[1]. Emphasis is on synthetic pathways and the structures of these compounds. Their use in oxidation and metathesis reactions is discussed together with a consideration of interactions with organic substrates. The compounds appear to have considerable untapped potential.

article Review
date_range 2024
language English
link Link of the paper
format_quote
H
Halim Md.
G
Guo Zhifang
B
Blair Victoria
D
Deacon Glen
J
Junk Peter
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Featured Keywords
Lanthanoids
Rare earths
Grignard reagents
Synthesis
Structures
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