T
Tang, Wei
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Photocatalytic Reduction of Nitrobenzene to Aniline by an Intriguing {Ru(C6H6)}-Based Heteropolytungstate

Abstract

In this paper, we have successfully synthesized a structurally novel heteropolytungstate via coordination of four {Ru(C6H6)} and trivacant {TeW9O33} clusters, formulated as Cs4Na2H2[Te2W20O72(H2O){(C6H6)Ru}(4)]12H(2)O (1). Compound 1 inherited the strong absorption of [Ru(C6H6)Cl-2](2) in the visible region and {TeW9O33} in the UV region, providing a good basis for photocatalysis. As expected, compound 1 showed good photocatalytic activity in the visible-light-driven reduction of nitrobenzene using N2H4H2O as a reductant with a yield of 99.8%, a high turnover number (TON = 330), and a high turnover frequency (TOF = 24 h(-1)). The cyclic experiment of nitrobenzene reduction indicated that compound 1 was an effective and stable heterogeneous catalyst. Finally, the nitrobenzene reduction pathway was affirmed using condensation with azobenzene as a reaction intermediate based on control experiments.

article Article
date_range 2024
language English
link Link of the paper
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T
Tang Wei
L
Liu Yanan
J
Jin Yuzhen
W
Wang Yuting
S
Shi Weixia
M
Ma Pengtao
N
Niu Jingyang
W
Wang Jingping
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